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Title: Field exploration of coupled hydrological and biogeochemical catchment responses and a unifying perceptual model

Authored by: Ocampo, C.J., Sivapalan, M. and Oldham, C.E.

Abstract:

This work presents the details of a focused field experiment carried out to understand the coupled processes of runoff generation and biogeochemical cycling in an agricultural catchment in Western Australia, with a particular focus on NO 3 cycling and transport. Detailed hydrometric, chemical, and geochemical data corresponding to a shallow perched aquifer along a topo-sequence in the hillslope helped identify the existence of two hydrologically and chemically distinct landscape units, i.e., upland and riparian zones. Riparian zones control the catchment storm response while upland zones can be considered as storage units, controlling the base flow component of streamflow. The biogeochemical role and functioning of these landscape units are also clear. Upland

zones constitute the sources of NO 3 and participate in down-slope transport, while riparian areas act as sinks for NO 3 and are responsible for its depletion. The experimental results highlighted the critical role of the shallow perched aquifer whose spaceÅ|time dynamics governed the periodic connection and disconnection between riparian and upland zones, which have a significant impact on the catchment s hydrological and hydrochemical responses. The role of topography was also highlighted, as different mechanisms of NO 3 attenuation in the riparian zones are possible depending on the steepness of the hillslope, with differences in slope leading to

different velocities and flow rates and impacting on relative dominance of the different mechanisms of NO 3 depletion. These detailed analyses have helped us to develop a ÅeÅeunifying perceptual modelÅfÅf of the coupled hydrological and biogeochemical response of Susannah Brook catchment, which will advance our ability to generalize these results to other hillslopes, and eventually to other catchments in the region.

2005 Elsevier Ltd. All rights reserved.

Reference: Ocampo, C.J., Sivapalan, M. and Oldham, C.E., 2006, Field exploration of coupled hydrological and biogeochemical catchment responses and a unifying perceptual model, Advances in Water Resources, special issue on 'Experimental Hydrology' (Editors: Jan Hopmans and Greg Pasternak), , 29 (2): 161-180

Keywords: Hillslope hydrology; Topography; Hydrologic connectivity; Riparian zone; Nitrogen cycling; Field experiments

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